Caffeine is a natural element of
coffee. Decaffeinated coffee is made from the same beans as
regular coffee. The difference is the process used to
remove caffeine.
Although the label states that the coffee is
decaffeinated, it is impossible to remove all the caffeine.
There is generally 3% of the caffeine left in the coffee.
The decaffeination process is performed on unroasted (green)
beans. The beans are steamed and then rinsed in a solvent
such as ethyl acetate. This chemical has been proven to be a
natural solvent. The process is repeated until it meets either
the international standard of removing 98% of the caffeine or
the European Union standard of being 99.9% caffeine free. There
are several methods used for this process.
The Roselius process was invented by Ludwig Roselius and
Karl Wimmer in 1903. Coffee beans were steamed in a salt water
solution and benzene was used as a solvent to remove the
caffeine. Brands which used this method were Cafe Sanka in
France and Sanka in the United States. This process is no
longer used due to health concerns.
The Swiss Water Decaffeinated Coffee Company developed a
method by which a batch of unroasted beans is soaked in
hot water to release the caffeine. The process continues until
all the caffeine and coffee solids are released into the water.
The beans are discarded. The water passes through a carbon
filter which traps the caffeine molecules but allows the water and the coffee
solids to pass through. The caffeine free water is passed
through a filtration device and new beans are added. The
process is repeated until the caffeine from the new
beans is released. The coffee produced from this method is
99.9% caffeine free.
The use of ethyl acetate is considered a natural process
because the chemicals are found in various fruits and
vegetables. The beans are steamed for thirty minutes and
then rinsed with the ethyl acetate. After the solvent is
drained, the beans are steamed for an additional ten hours to
remove any residual solvent.
Another process uses carbon dioxide. The beans are steamed
and then soaked in a liquid bath of carbon dioxide under
pressure. After they are thoroughly soaked, the pressure is
reduced allowing the carbon dioxide to evaporate. An
alternative is to run the carbon dioxide through either water
or charcoal filters to remove the caffeine.
Although decaffeinated coffee still contains some caffeine,
it is reduced enough so that people who can not drink
coffee with caffeine allows them to still enjoy their favorite
drink. Because the product label says the coffee is
decaffeinated, that does not mean you can drink cup after
cup and not feel the effects. Based on research, drinking
five to ten cups of decaffeinated coffee would be the same as
drinking one or two cups of coffee with caffeine.
A breakthrough occurred in 2004. A naturally caffeine-free
bean was discovered in Ethiopia. This may change how
decaffeinated coffee is processed.